A highly active and stable organic-inorganic combined solid acid for the transesterification of glycerol under mild conditions
نویسندگان
چکیده
Solid acid catalyst plays a crucial role in the petroleum refinery industry and bio-refinery technology. In this work, p-phenolsulfonic (PSA) was successfully grafted onto surface of KH560-modified zirconium phosphate (K-ZrP) facile routine. The structure property organic-inorganic combined solid PSA/K-ZrP-x were characterized via XRD, FTIR, 13C solid-state NMR, TG, N2 adsorption-desorption, SEM, pyridine-adsorption FTIR XPS technologies. characterization results showed that KH560 can bond with ZrP promote grafting PSA on K-ZrP condensation reaction between its epoxy ring phenolic hydroxyl group PSA. Consequently, PSA/K-ZrP-2 exhibited excellent performance stability transesterification glycerol methyl acetate among tested H3PW12O40, Amberlyst-45, HBEA, HZSM-5, ZrP, AlCl3 FeCl3 catalysts. calculated conversion reached 81.3% 97.9% selectivity for monoacetin (MAG) diacetin (DAG) 2.2% dosage [H+] at 100 °C 4 h. highest specific activity 24028.2 mg-glycerol/g-cat/h short time (at 0.17 h), it could be recycled five times without obvious deactivation.
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potassium carbonate: a highly efficient catalyst for the acylation of alcohols, phenols and thiols under mild conditions
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ژورنال
عنوان ژورنال: Chinese Journal of Catalysis
سال: 2021
ISSN: ['0253-9837', '1872-2067']
DOI: https://doi.org/10.1016/s1872-2067(21)63811-1